General notes on disconnecting battery:

WARNING: This page does not describe the selected car, but rather 17 other vehicles, including the 2006 BMW 330Ci, 2006 BMW 325Ci, 2005 BMW 330xi, 2005 BMW 330i, and 2005 BMW 330Ci. However, it is still accessible from the selected car via links, so may be relevant.

Do not disconnect battery leads and leads from alternator and starter motor while engine is running.
Cars with IBS on battery negative terminal:
Do not under any circumstances pull/lever off pole shoes by force.

Do not under any circumstances release socket-head cap screw of IBS.
Detach terminal of battery negative lead from car battery and second battery if fitted. Cover battery negative terminal(s) and secure.
When work is carried out on the electrical system, faults may be caused in the fault memories of some control units when the battery is connected.
When fitting terminal for battery negative lead.