Diagnostic Aids
WARNING: This page is about a different car, the 1995 Chevrolet Corvette. However, it is still accessible from the selected car via links, so may be relevant.
Code 66 sets when signal voltage falls outside normal sensor range and is not due to a A/C system problem. If problem is intermittent, check for opens or shorts in harness and poor connections. If wiring is okay, replace pressure sensor. If code resets, replace PCM.